TY  - JOUR
AU  - Carballo, R.
AU  - Castiñeiras, A.
AU  - Covelo, B.
AU  - Lago, A.B.
AU  - Vázquez-López, E.M.
AU  - Gómez-Paz, O.
AU  - Balboa, S.
AU  - Prieto, I.
T1  - Chiral and achiral 1D copper(ii) coordination polymers based on glycolato and chelating aromatic diamine ligands
LA  - eng
PY  - 2018
SP  - 2455
EP  - 2464
T2  - CrystEngComm
SN  - 1466-8033
VL  - 20
IS  - 17
PB  - Royal Society of Chemistry
AB  - Achiral glycolic acid and chelating aromatic diamine ligands were employed at room temperature to prepare five 1D copper(ii) coordination polymers which were structurally characterized. The polymers ∞1{[Cu(HG)(dipyam)](HG)} (1) (dipyam = 2,2′-dipyridylamine) and ∞1[Cu(HG)(ClO4)(NN)] (NN = 2,2′-bipyridine (2), NN = 1,10-phenanthroline (3)) adopt homochiral helical structures in the crystal state and undergo spontaneous chiral resolution in the solid state. On the other hand, the polymers containing bidepronated glycolato ligand G, ∞1{[Cu(G)(dipyam)]·H2O} (1a), obtained from a solution of 1 in MeOH/iPrOH and ∞1{[Cu2(μ-G)(ClO4)(H2O)(dipyam)2](ClO4)(H2O)2} (4b) are achirals. Crystals of 4b have been obtained together with crystals of the molecular complex [Cu(HG)(H2O)(dipyam)](ClO4) (4a). Analysis by Hirshfeld surface generation and two-dimensional fingerprinting was carried out to study the nature of the interactions and their contributions towards the crystal packing.
DO  - 10.1039/c8ce00279g
UR  - https://portalciencia.ull.es/documentos/5da708362999527d16bbc883
DP  - Dialnet - Portal de la Investigación
ER  -