TY  - JOUR
AU  - Cuevas, A.
AU  - Geis, L.
AU  - Pintos, V.
AU  - Chiozzone, R.
AU  - Sanchíz, J.
AU  - Hummert, M.
AU  - Schumann, H.
AU  - Kremer, C.
T1  - Synthesis, molecular structure and magnetic properties of a rhenium(IV) compound with catechol
LA  - eng
PY  - 2009
SP  - 80
EP  - 84
T2  - Journal of Molecular Structure
SN  - 0022-2860
VL  - 921
IS  - 1-3
AB  - A novel Re(IV) complex containing catechol as ligand has been prepared and characterized. The crystal structure of (HNEt3)(NBu4)[ReCl4(cat)]·H2cat was determined. The rhenium ion presents a distorted octahedral geometry, being bonded to a bidentate catecholate group and four chloride anions. The magnetic properties of the complex were studied, a /2D/ (the energy gap between ±3/2 and ±1/2 Kramers doublets) value of 190(10) cm-1. This is the largest /2D/ value reported for Re(IV) up to now. © 2008 Elsevier B.V. All rights reserved.
DO  - 10.1016/j.molstruc.2008.12.031
UR  - https://portalciencia.ull.es/documentos/5e3c356329995246bbf5d531
DP  - Dialnet - Portal de la Investigación
ER  -