TY - JOUR AU - Fabelo, O. AU - Cañadillas-Delgado, L. AU - Pasán, J. AU - Díaz-Gallifa, P. AU - Labrador, A. AU - Ruiz-Pérez, C. T1 - Dryness sensitive porous 3d-4f metal-organic framework with unusual dynamic behaviour LA - eng PY - 2012 SP - 765 EP - 767 T2 - CrystEngComm SN - 1466-8033 VL - 14 IS - 3 AB - A new three-dimensional heteronuclear metal-organic framework has been synthesized using the 1,2,4,5-benzenetetracarboxylate ligand as a linker and Pr(iii)-Cu(ii) dinuclear units as nodes. The resulting structure shows an unexpected dynamic behaviour, where the volume of the crystal structure is shrunk by 11.5% in a dryness atmosphere. © 2012 The Royal Society of Chemistry. DO - 10.1039/c1ce06210g UR - https://portalciencia.ull.es/documentos/5e3c379729995246bbf5e85c DP - Dialnet - Portal de la Investigación ER -