TY  - JOUR
AU  - Díaz-Gallifa, P.
AU  - Fabelo, O.
AU  - Pasán, J.
AU  - Cañadillas-Delgado, L.
AU  - Lloret, F.
AU  - Julve, M.
AU  - Ruiz-Pérez, C.
T1  - Two-dimensional 3d-4f heterometallic coordination polymers: Syntheses, crystal structures, and magnetic properties of six new Co(II)-Ln(III) compounds
LA  - eng
PY  - 2014
SP  - 6299
EP  - 6308
T2  - Inorganic Chemistry
SN  - 1520-510X
VL  - 53
IS  - 12
PB  - American Chemical Society
AB  - Six new heterometallic cobalt(II)-lanthanide(III) complexes of formulas [Ln(bta)(H2O)2]2[Co(H2O) 6]·10H2O [Ln = Nd(III) (1) and Eu(III) (2)] and [Ln2Co(bta)2(H2O)8] n·6nH2O [Ln = Eu(III) (3), Sm(III) (4), Gd(III) (5), and Tb(III) (6)] (H4bta = 1,2,4,5-benzenetretracaboxylic acid) have been synthesized and characterized via single-crystal X-ray diffraction. 1 and 2 are isostructural compounds with a structure composed of anionic layers of [Ln(bta)(H2O)2]nn- sandwiching mononuclear [Co(H2O)6]2+ cations plus crystallization water molecules, which are interlinked by electrostatic forces and hydrogen bonds, leading to a supramolecular three-dimensional network. 3-6 are also isostructural compounds, and their structure consists of neutral layers of formula [Ln2Co(bta)2(H2O)8] n and crystallization water molecules, which are connected through hydrogen bonds to afford a supramolecular three-dimensional network. Heterometallic chains formed by the regular alternation of two nine-coordinate lanthanide(III) polyhedra [Ln(III)O9] and one compressed cobalt(II) octahedron [Co(II)O6] along the crystallographic c-axis are cross-linked by bta ligands within each layer of 3-6. Magnetic susceptibility measurements on polycrystalline samples for 3-6 have been carried out in the temperature range of 2.0-300 K. The magnetic behavior of these types of Ln(III)-Co(II) complexes, which have been modeled by using matrix dagonalization techniques, reveals the lack of magnetic coupling for 3 and 4, and the occurrence of weak antiferromagnetic interactions within the Gd(III)-Gd(III) (5) and Tb(III)-Tb(III) (6) dinuclear units through the exchange pathway provided by the double oxo(carboxylate) and double syn-syn carboxylate bridges. © 2014 American Chemical Society.
DO  - 10.1021/ic5008582
UR  - https://portalciencia.ull.es/documentos/5e3c395129995246bbf5f2a7
DP  - Dialnet - Portal de la Investigación
ER  -