TY - JOUR AU - Hernández Molina, R. AU - Agirretxu, A. AU - González-Platas, J. T1 - Synthesis and structure of [CuI(3-methyl-2-phenylpiridine)2] with intermolecular stacking interactions LA - eng PY - 2014 SP - 1478 EP - 1483 T2 - Journal of Structural Chemistry SN - 0022-4766 VL - 55 IS - 8 PB - Maik Nauka Publishing / Springer SBM AB - The preparation of a copper(I) iodide complex with a N-donor ligand 3-methyl-2-phenylpyridine of formula [CuI(3-methyl-2-phenylpiridine)2] is described. The isolated complex was characterized by elemental analyses, IR spectroscopy and crystallographic studies. Single crystal X-Ray diffraction analysis of the complex reveal their monomeric tri-coordinated nature. The coordination polyhedron around the copper center may be described as a distorted trigonal planar geometry. The Cu-N distances for this compound are 1.984(7) Å and 1.982(7) Å, while the Cu-I distance is 2.5507(9) Å. DO - 10.1134/S0022476614080150 UR - https://portalciencia.ull.es/documentos/5e3c39a029995246bbf5f530 DP - Dialnet - Portal de la Investigación ER -