TY  - JOUR
AU  - Gushchin, A.L.
AU  - Hernandez-Molina, R.
AU  - Anyushin, A.V.
AU  - Gallyamov, M.R.
AU  - Gonzalez-Platas, J.
AU  - Moroz, N.K.
AU  - Sokolov, M.N.
T1  - Synthesis, structure and NMR studies of trinuclear Mo3S4 clusters coordinated with dithiophosphate and chiral carboxylate ligands
LA  - eng
PY  - 2016
SP  - 7612
EP  - 7619
T2  - New Journal of Chemistry
SN  - 1369-9261
VL  - 40
IS  - 9
PB  - Royal Society of Chemistry
AB  - New chiral cluster complexes containing (S)-mandelate and (S)-phenyllactate ligands, [Mo3S4(dtp)3(μ-(S)-mandelate)(py)] (1) and [Mo3S4(dtp)3(μ-(S)-phenyllactate)(py)], were prepared from [Mo3S4(dtp)3(μ-dtp)(H2O)] (dtp = (EtO)2PS2) by ligand substitution. The crystal structures of 1 and 2 were determined by X-ray diffraction. Detailed variable-temperature 31P{1H} and 1H NMR studies of solutions of 1 and 2 in non-coordinating solvents (CDCl3, CD2Cl2) demonstrated three dynamic processes at the Mo-Py coordination site: diastereomer interconversion [(PS) to (MS)] which is inhibited at low temperatures; pyridine rotation around the Mo-py bond (180°-flip), and pyridine exchange in the presence of added pyridine. Activation parameters for all exchange processes have been estimated.
DO  - 10.1039/C6NJ01303A
UR  - https://portalciencia.ull.es/documentos/5e3c3c5c29995246bbf60730
DP  - Dialnet - Portal de la Investigación
ER  -