Metal complexes of polytopic hydrazone ligandssynthesis, characterization and properties
- Rodríguez Hermida, Sabina
- Ana Belén Lago Blanco Co-director
- Ezequiel M. Vázquez López Co-director
Universidade de defensa: Universidade de Vigo
Fecha de defensa: 21 de xuño de 2013
- Roberto Cortés Montero Presidente/a
- Rosa Carballo Rial Secretario/a
- Nora Kulak Vogal
Tipo: Tese
Resumo
Six organic ligands based on bis-aroylhydrazone skeleton have been designed and synthesized. Their coordinative behaviour towards different metallic centres such as Cu(I), Cu(II), Co(II), Ni(II) and Zn(II) has been investigated. Special effort is done to obtain single-crystals in order to determine the crystal structure of the compounds and their supramolecular association and arrangement at the solid state. The properties of the compounds obtained depending on their intrinsic characteristics have been also investigated, such as, for example, luminescence and dynamism.