TY  - JOUR
AU  - González, A.G.
AU  - Galindo, A.
AU  - Afonso, M.M.
AU  - Mansilla, H.
AU  - Palenzuela, J.A.
AU  - Rodriguez, M.A.G.
AU  - Martinez-Ripoll, M.
T1  - The biomimetic synthesis of trans-(1β-h,5α-h)-guaianolides
LA  - eng
PY  - 1988
SP  - 4575
EP  - 4584
T2  - Tetrahedron
SN  - 0040-4020
VL  - 44
IS  - 14
AB  - 1-epigallicin 11 underwent biomimetic cyclization to trans-(1β-H,5α-H)-guaianolide 22,the stereoespecificity of this cyclization being credited to the fact that it took place via the reacting TC conformation 27. The epimeric nor-guaianolides 15 and 17 were prepared and their rearrangements studied. The biogenetic implications of these processes are discussed. © 1988.
DO  - 10.1016/S0040-4020(01)86160-3
UR  - https://portalciencia.ull.es/documentos/5ee0bfef2999527595f95d29
DP  - Dialnet - Portal de la Investigación
ER  -