TY  - JOUR
AU  - Carballo, R.
AU  - Covelo, B.
AU  - Fernández-Hermida, N.
AU  - García-Martínez, E.
AU  - Lago, A.B.
AU  - Vázquez-López, E.M.
T1  - Solid state coordination chemistry of copper(II) lactate complexes with the twisted ligands 4,4′-dipyridyldisulfide and bis(4-pyridylthio)methane
LA  - eng
PY  - 2008
SP  - 427
EP  - 432
T2  - Journal of Molecular Structure
SN  - 0022-2860
VL  - 892
IS  - 1-3
AB  - The 1D coordination polymer 1∞[Cu(HL)2(SS)]·4H2O (1) and the molecular compound [Cu2(HL)4(SCS)3] (2) [where SS = 4,4′-dipyridyldisulfide, SCS = bis(4-pyridylthio)methane and HL = lactate] have been prepared by reaction of the SS and SCS ligands with copper(II) lactate. X-ray structural analysis revealed that in 1 the SS ligand acts as an N,N′-bis(monodentate) system, whereas in 2 the SCS ligand acts in an N,N′-bis(monodentate) manner to produce a dinuclear compound and also as a monodentate terminal ligand. Hydrogen bonding interactions join the polymeric chains of 1 and the molecules of 2 to generate 3D networks. The thermal behaviour of the two compounds was investigated and the reversibility of the dehydration-rehydration processes in 1 was also evaluated. © 2008 Elsevier B.V. All rights reserved.
DO  - 10.1016/J.MOLSTRUC.2008.06.009
UR  - https://portalciencia.ull.es/documentos/5ee0c0bd2999527595f9605e
DP  - Dialnet - Portal de la Investigación
ER  -