Absolute Structures of Two New C<sub>13</sub>-Norisoprenoids from Apollonias barbujana

  1. Pérez, Cirilo 1
  2. Trujillo, Juan 1
  3. Almonacid, Luz N. 1
  4. Trujillo, Jesus 1
  5. Navarro, Eduardo 1
  6. Alonso, Simeona J. 1
  1. 1 Universidad de La Laguna
    info

    Universidad de La Laguna

    San Cristobal de La Laguna, España

    ROR https://ror.org/01r9z8p25

Revista:
Journal of Natural Products

ISSN: 0163-3864,  1520-6025

Año de publicación: 1996

Volumen: 59

Número: 1

Páginas: 69-72

Tipo: Artículo

DOI: 10.1021/NP9600154 GOOGLE SCHOLAR lock_openAcceso abierto editor

Otras publicaciones en: Journal of Natural Products

Resumen

Two new (213-norisoprenoid compounds, (3S,5R,6S,9R)-3,6-dihydroxy-5,6-dihydro-,8-ionol(l)and(3S,4S,5S,6S,9S)-3,4-dihydroxy-5,6-dihydro-P-ionol(2),were isolated from the leaves of ApoZ-Zonias barbujana. The absolute structures were determined by spectroscopic methods andchemical transformations. (3S,4S,5S,6S,9R)-3,4-Dihydroxy-5,6-dihydro-P-ionol(3)was alsoisolated, the structure of which has been determined by X-ray analysis and whose lH-NMR,13C-NMR, and MS data a r e reported herein.

Referencias bibliográficas

  • Bormuler C., (1903), Engl. Bot. Jahrb., 33, pp. 420
  • Bramwell, D.; Bramwell, Z.Flores Silvestres de las Islas Canarias; Rueda:  Madrid, 1990; p 104.
  • Watt, M.The Medicinal and Poisonous Plants of Southern and Eastern Africa; E & S. Livingstone Ltd.  London, 1962; p 529.
  • Walter, H. L.Medicinal Botany. John Wiley & Sons:  New York, 1977.
  • Salesianos de Chile.La salud por medio de las Plantas Medicinales; New York, Life Insurance Co.  New York, 1929; p 364.
  • Kiang A. K., (1962), J. Chem. Soc., pp. 4338, 10.1039/jr9620004338
  • Ohloff G., (1978), Prog. Chem. Org. Nat. Prod., 35, pp. 431
  • Nykänen L., (1983), Aroma of Beer, Wine and Distilled Alcoholic Beverages
  • Shiraga Y., (1988), Tetrahedron, 4, pp. 4703, 10.1016/S0040-4020(01)86173-1
  • Otsuka H., (1992), Planta Med., 58, pp. 373, 10.1055/s-2006-961489
  • Fujimori T., (1975), Agric. Biol. Chem., 39, pp. 913
  • Fujimori T., (1974), Agric. Biol. Chem., 38, pp. 891
  • Harada N., (1981), J. Am. Chem. Soc., 103, pp. 5590, 10.1021/ja00408a061
  • Otsuka H., (1993), Chem. Pharm. Bull., 41, pp. 1860, 10.1248/cpb.41.1860
  • Rodríguez M. L., (1992), Acta Crystallogr., 48, pp. 2192
  • Pauli N., (1990), Helv. Chim. Acta, 73, pp. 578, 10.1002/hlca.19900730305