Metal complexes of polytopic hydrazone ligandssynthesis, characterization and properties
- Rodríguez Hermida, Sabina
- Ana Belén Lago Blanco Co-Doktormutter
- Ezequiel M. Vázquez López Co-Doktorvater/Doktormutter
Universität der Verteidigung: Universidade de Vigo
Fecha de defensa: 21 von Juni von 2013
- Roberto Cortés Montero Präsident/in
- Rosa Carballo Rial Sekretär/in
- Nora Kulak Vocal
Art: Dissertation
Zusammenfassung
Six organic ligands based on bis-aroylhydrazone skeleton have been designed and synthesized. Their coordinative behaviour towards different metallic centres such as Cu(I), Cu(II), Co(II), Ni(II) and Zn(II) has been investigated. Special effort is done to obtain single-crystals in order to determine the crystal structure of the compounds and their supramolecular association and arrangement at the solid state. The properties of the compounds obtained depending on their intrinsic characteristics have been also investigated, such as, for example, luminescence and dynamism.